The discovery of bronze enabled people to create metal objects that were harder and more durable than previously possible. Bronze tools, weapons, armor, and building materials such as decorative tiles were harder and more durable than their stone and copper ("Chalcolithic") predecessors. Initially, bronze was made out of copper and arsenic, forming arsenic bronze, or from naturally or artificially mixed ores of copper and arsenic, with the earliest artifacts so far known coming from the Iranian plateau in the 5th millennium BCE. It was only later that tin was used, becoming the major non-copper ingredient of bronze in the late 3rd millennium BCE.
Tin bronze was superior to arsenic bronze in that the alloying process could be more easily controlled, and the resulting alloy was stronger and easier to cast. Also, unlike arsenic, metallic tin and fumes from tin refining are not toxic. The earliest tin-alloy bronze dates to 4500 BCE in a Vinča culture site in Pločnik (Serbia).[9] Other early examples date to the late 4th millennium BCE in Egypt, Susa (Iran) and some ancient sites in China, Luristan (Iran) and Mesopotamia (Iraq).[citation needed]
Ores of copper and the far rarer tin are not often found together (exceptions include Cornwall in Britain, one ancient site in Thailand and one in Iran), so serious bronze work has always involved trade. Tin sources and trade in ancient times had a major influence on the development of cultures. In Europe, a major source of tin was the British deposits of ore in Cornwall, which were traded as far as Phoenicia in the eastern Mediterranean.
In many parts of the world, large hoards of bronze artifacts are found, suggesting that bronze also represented a store of value and an indicator of social status. In Europe, large hoards of bronze tools, typically socketed axes (illustrated above), are found, which mostly show no signs of wear. With Chinese ritual bronzes, which are documented in the inscriptions they carry and from other sources, the case is clear. These were made in enormous quantities for elite burials, and also used by the living for ritual offerings.
Transition to iron
Though bronze is generally harder than wrought iron, with Vickers hardness of 60–258 vs. 30–80, the Bronze Age gave way to the Iron Age after a serious disruption of the tin trade: the population migrations of around 1200–1100 BCE reduced the shipping of tin around the Mediterranean and from Britain, limiting supplies and raising prices. As the art of working in iron improved, iron became cheaper and improved in quality. As cultures advanced from hand-wrought iron to machine-forged iron (typically made with trip hammers powered by water), blacksmiths learned how to make steel. Steel is stronger than bronze and holds a sharper edge longer.
Bronze was still used during the Iron Age, and has continued in use for many purposes to the modern day.
